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The Southern Ocean plays an important role in determining atmospheric carbon dioxide (CO 2 ), yet estimates of air-sea CO 2 flux for the region diverge widely. In this study, we constrained Southern Ocean air-sea CO 2 exchange by relating fluxes to horizontal and vertical CO 2 gradients in atmospheric transport models and applying atmospheric observations of these gradients to estimate fluxes. Aircraft-based measurements of the vertical atmospheric CO 2 gradient provide robust flux constraints. We found an annual mean flux of –0.53 ± 0.23 petagrams of carbon per year (net uptake) south of 45°S during the period 2009–2018. This is consistent with the mean of atmospheric inversion estimates and surface-ocean partial pressure of CO 2 ( P co 2 )–based products, but our data indicate stronger annual mean uptake than suggested by recent interpretations of profiling float observations. 

The air‐sea exchange of oxygen (O₂) is driven by changes in solubility, biological activity, and circulation. The total air‐sea exchange of O₂has been shown to be closely related to the air‐sea exchange of heat on seasonal timescales, with the ratio of the seasonal flux of O₂to heat varying with latitude, being higher in the extratropics and lower in the subtropics. This O₂/heat ratio is both a fundamental biogeochemical property of air‐sea exchange and a convenient metric for testing earth system models. Current estimates of the O₂/heat flux ratio rely on sparse observations of dissolved O₂, leaving it fairly unconstrained. From a model ensemble we show that the ratio of the seasonal amplitude of two atmospheric tracers, atmospheric potential oxygen (APO) and the argon‐to‐nitrogen ratio (Ar/O₂), exhibits a close relationship to the O₂/heat ratio of the extratropics (40–). The amplitude ratio,/, is relatively constant within the extratropics of each hemisphere due to the zonal mixing of the atmosphere./is not sensitive to atmospheric transport, as most of the observed spatial variability in the seasonal amplitude ofAPO is compensated by similar variations in(Ar/). From the relationship between/heat and/in the model ensemble, we determine that the atmospheric observations suggest hemispherically distinct/heat flux ratios of 3.30.3 and 4.70.8 nmolbetween 40 andin the Northern and Southern Hemispheres respectively, providing a useful constraint forand heat air‐sea fluxes in earth system models and observation‐based data products.

 

We present airborne observations of the vertical gradient of atmospheric oxygen (δ(O₂/N₂)) and carbon dioxide (CO₂) through the atmospheric boundary layer (BL) over the Drake Passage region of the Southern Ocean, during the O₂/N₂Ratio and CO₂Airborne Southern Ocean Study, from 15 January to 29 February 2016. Gradients were predominately anticorrelated, with excesses ofδ(O₂/N₂) and depletions of CO₂found within the boundary layer, relative to a mean reference height of 1.7 km. Through analysis of the molar ratio of the gradients (GR), the behavior of other trace gases measured in situ, and modeling experiments with the Community Earth System Model, we found that the main driver of gradients was air‐sea exchange of O₂and CO₂driven by biological processes, more so than solubility effects. An exception to this was in the eastern Drake Passage, where positive GRs were occasionally observed, likely due to the dominance of thermal forcing on the air‐sea flux of both species. GRs were more spatially consistent than the magnitudes of the gradients, suggesting that GRs can provide integrated process constraints over broad spatial scales. Based on the model simulation within a domain bounded by 45°S, 75°S, 100°W, and 45°W, we show that the sampling density of the campaign was such that the observed mean GR (± standard error), −4.0± 0.8 mol O₂per mol CO₂, was a reasonable proxy for both the mean GR and the mean molar ratio of air‐sea fluxes of O₂and CO₂during the O₂/N₂Ratio and CO₂Airborne Southern Ocean Study.